Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

东北三省全面振兴的社会经济支撑能力评估

在解析支撑能力和东北问题特点的基础上，从“创新、协调、绿色、开放、共享”五大理念出发建立全面振兴社会经济支撑能力评价指标体系和综合评价方法，以地级市为单元对东北三省进行评估。研究发现：各地市社会经济支撑能力差异显著，哈大沿线核心城市的支撑能力较强，西翼城市以及朝阳、七台河、绥化、葫芦岛、铁岭、双鸭山和鹤岗等资源型城市支撑能力较弱。因此未来东北地区在振兴政策的区域分布上应有所侧重，对不同地区施以不同的振兴或扶持政策。在创新、绿色、开放方面需要集中力量重点突破，而在体制机制改革和共享服务建设方面需要全面覆盖，并重点加强黑龙江北部和辽宁、吉林西翼城市的共享能力建设。     

环渤海地区海洋经济增长质量空间溢出效应研究

海洋经济向质量效益型转变是建设海洋强国的新要求。通过构建海洋经济?地理距离空间权重矩阵对2000—2014年环渤海地区17个沿海地级市海洋经济增长质量主体的空间交互作用及空间效应进行研究；借助空间计量模型对海洋经济增长质量空间效应影响因素进行甄别。研究表明：① 环渤海地区海洋经济增长质量主体呈显著空间相关性，存在空间交互作用；② 海洋经济增长质量存在空间溢出的正反馈效应。影响因素中对环渤海地区海洋经济增长质量的直接贡献强度排序为：海洋环境>海洋产业>海洋人才>海洋资本>海洋科技，对其他地区溢出效应影响的排序为：海洋基建>海洋人才>海洋资本。研究为环渤海地区海洋政策制定提供一定参考依据。     

滨海城市竖向避难场所选址可靠性评价与若干问题探讨

关注滨海城市竖向避难场所的选址可靠性问题，首先深化确立“竖向避难场所”概念；然后构建竖向避难场所选址可靠性评价模型，综合自然地理要素和建成环境要素，从与灾害直接作用相关的选址暴露性、与应急交通相关的选址敏感性、与应急服务相关的选址适应性3个维度展开，搭建3级评价指标体系；再以天津滨海新区为例、聚焦滨海城市潮洪灾害和人口安全矛盾的集核——临港城区展开实证研究，借助ArcGIS分类与可视化发现：高低可靠性选址之间具有明显的空间分异，可以分解为灾害暴露性的“近岸高?远岸低”分异、交通敏感性的“外围高?中心低”分异、服务适应性的“中心与沿河高?外围低”兼“近港高?远港低”分异。同时发现：商业设施用地选址价值较高，在高可靠性选址中占比第一；中小学和社会福利设施用地选址价值最高，在高可靠性选址中占比第二；文化科研和娱乐康体设施用地在高可靠性选址中占比最小。针对临港城区实证研究结果，提出滨海城市竖向避难场所选址及可靠性提升对策。     

游客-环境互动视角下旅游者目的地环境恢复性效应

日常生活环境和旅游目的地环境都可以为个体提供恢复的机会，不同环境的属性特征导致不同程度的恢复。为了探究环境类型与恢复性效应之间的关系及停留时间的调节作用，文章采用问卷调查方式，利用配对样本t检验和混合设计方差分析相结合的方法，探讨游客在不同环境中的恢复性效应，并对这一现象提供心理上的解释。结果表明：1）恢复体验的4个维度（放松体验、心理脱离、掌握体验、控制体验）在旅游目的地环境中的得分均高于日常生活环境。2）掌握和控制体验维度在城市旅游目的地中的变化程度高于乡村旅游目的地，两种类型目的地的放松和心理脱离维度差异较小。3）随着在目的地停留时间的延长，乡村旅游目的地放松体验和心理脱离维度变化程度高于城市旅游目的地，两种类型目的地环境恢复性效应会相互靠近。因此，游客的环境恢复性效应不仅受到环境和目的地类型的影响，同时还与游客的适应程度有关，且受到其停留时间的调节作用。     

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。     

Salinivibrio sp.YH4胞外丝氨酸蛋白酶EYHS耐盐性及生物信息学分析

摘要：目的 探讨菌株Salinivibrio sp.YH4分泌的丝氨酸蛋白酶EYHS的耐盐性及结构特征。方法 明胶底物酶谱法分析EYHS的耐盐性。应用生物信息学手段对EYHS及6种耐盐的S8家族丝氨酸蛋白酶结构特征进行分析。结果 EYHS在4 mol/L的NaCl溶液中仍具有活性，属于耐盐蛋白酶。EYHS及6种S8家族丝氨酸蛋白酶分子表面的loop区等无规则卷曲所占比例较高，α-螺旋与β-片层则主要位于酶分子内部。EYHS分子表面酸性氨基酸含量较高，且具有弱疏水内核。多序列比对发现蛋白酶的催化三联体两侧存在高度保守的基序和保守的极性氨基酸及芳香族氨基酸，并存在多个保守的Gly与Ala。同源模建和表面电荷分布显示，α螺旋和β片层围成了蛋白酶的催化腔，EYHS活性中心包含由Asp32、His65与Ser215组成的催化三联体，且催化位点区域表面静电势为负。结论 上述结构特征可能有助于耐盐丝氨酸蛋白酶EYHS在高盐环境下维持其稳定性和适度柔性，并有助于其催化功能的发挥，为深入研究耐盐丝氨酸蛋白酶的高盐环境适应性提供了一定的理论依据。     

Simulations of the Impact of Lakes on Local and Regional Climate Over the Tibetan Plateau

ABSTRACT

Because of the high elevation and complex topography of the Tibetan Plateau (TP), the role of lakes in the climate system over the Tibetan Plateau is not well understood. For this study, we investigated the impact of lake processes on local and regional climate using the Weather Research and Forecasting (WRF) model, which includes a one-dimensional physically based lake model. The first simulation with the WRF model was performed for the TP over the 2000–2010 period, and the second was carried out during the same period but with the lakes filled with nearby land-use types. Results with the lake simulation show that the model captures the spatial and temporal patterns of annual mean precipitation and temperature well over the TP. Through comparison of the two simulations, we found that the TP lakes mainly cool the near-surface air, inducing a decreasing sensible heat flux for the entire year. Meanwhile, stronger evaporation produced by the lakes is found in the fall. During the summer, the cooling effect of the lakes decreases precipitation in the surrounding area and generates anomalous circulation patterns. In conclusion, the TP lakes cool the near-surface atmosphere most of the time, weaken the sensible heat flux, and strengthen the latent heat flux, resulting in changes in mesoscale precipitation and regional-scale circulation.     

Tracing the settlement region of massive floating green algae in the Yellow Sea

Outbreaks of large-scale green tides formed by Ulva prolifera in the Yellow Sea(YS)cause heavy ecological damages and huge economic losses.However,the ecological consequences of green tides remain poorly understood due to the lack of knowledge on the settlement region of massive green algae floating in the YS.In this study,we established a method to trace the settlement region of floating green algae,using 28-isofucosterol preserved in sediment as the specific biomarker for green algae.Sterols including 28-isofucosterol in surface sediment samples collected during an investigation in the YS and the Bohai Sea(BS)in August 2015 were analyzed using gas chromatography coupled with a mass spectrometer(GC-MS).Based on the content of 28-isofucosterol in sediment samples,the potential settlement region of loating green algae was identified in the sea area southeast to the Shandong Peninsula around the sampling site H06(122.66°E,36.00°N).This paper presents a first result on the settlement region of floating green algae in the YS for providing a solid basis to elucidate the ecological consequences of green tides in the area.     

Application of Glycerol Dialkyl Glycerol Tetraether Lipids in Paleoenvironment Reconstruction of Loess Deposits: A Review of Recent Progresses

The Glycerol Dialkyl Glycerol Tetraethers (GDGTs) occur ubiquitously in a wide range of environments, such as loess, peat, lake, soil, and ocean, which vary compositionally in response to environmental changes, and provide a series of biomarker proxies for paleoenvironmental reconstruction. This paper introduced the structures and biological sources of GDGTs, and reviewed the recent progresses of the application of the GDGTs proxies in the paleoenvironmental reconstruction of loess deposits. The main progresses include: \mathrm{①} The GDGTs proxies have been widely used in reconstructing the climate changes in loess deposits, and have established the temperature changes of last 800 ka for the Chinese Loess Plateau; \mathrm{②}Temperature variations in Chinese Loess Plateau displayed significant correlation with the Northern Hemisphere insolation, which may be also regulated by the surface vegetation conditions; and \mathrm{③} In the Chinese Loess Plateau, the increase in monsoon precipitation during the last deglaciation significantly lagged behind the rise of temperature. However, problems still exist in the current studies. For instance, the GDGTs-based temperature is likely overestimated, probably reflecting the temperature of warm season, and relationships between GDGT indices and climate factors are still unclear. In the future, the development of new proxies and more accurate regional calibrations based on the separation of 6- methyl GDGTs are expected to provide more reliable paleoenvironmental information, and will provide essential evidence for the evolution of hydrothermal pattern and mechanisms behind climate changes in different regions.